ajdelange wrote:*Tinseth publishes his formulas as F1 = (1-exp(-0.04*minutes)/4.15 which represents the time factor. Note that it has value 0.241 for long boil times. The other factor he calls the "bigness" factor; F2 = 1.65*0.000125^(SG-1). Note that for pure water (SG =1.000) this factor has a value of 1.65. Multiplying F1*F2 gives a maximum utilization of 39.7%. It would feel better to me if F1 = (1-exp(-0.04*minutes)/4.15/1.65 and F2 = 0.000125^(SG-1) so the two represent separate reductions in utilization but perhaps he has a good reason for doing it the way he did.
I agree that the Tinseth formulae makes more sense than the other two in most respect, particularly when plotted out and compared. The fact that there are no offsets or discontinuities in the Tinseth formula is the most obvious point in its favour. However, perhaps Mr. Tinseth's maths were not up to it, because his formula is more complicated than it needs to be, and has several interrelated constants all muddled together such that it is not intuitive as what needs to be done to adjust it to match various peoples systems or experiences.
Some time ago, for something else that I was doing, after making similar observations to Mr. Delange, I simplified Tinseth's approach and split it into distinct sections to make it much simpler to adjust.
This is how it ended up:
Utilisation = Su x Gc x Bc
Where:
Su = Start utilisation, in per cent. This is a figure that represents an upper limit for utilisation - the very maximum utilisation that could (possibly) be achieved under ideal, or better-than-ideal, conditions (such as infinite boil time and zero original gravity). To match Tinseth this is set to 39.75. This number happens to match the 39.7 mentioned by Mr. Delange (except that I came up with it by trial and error - I did not see the relationship that Mr. Delange pointed out, so it shows that my maths are not that good either). This figure is then modified by the other two factors to incorporate his "bigness factor" and the boil-time factor.
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Gc = Gravity Compensation Factor, represents Tinseth's Bigness Factor - a number between 0 and 1. This is generated by an exponential function. It seems that Tinseth was not aware that his function was exponential, judging by his convoluted formula, but when one examines it, exponential is what it turns out to be. In my version it is given by: Gc = e^(-degrees_grav /Scale_Factor) The degrees gravity is the O.G. expressed in degrees (1.045 = 45 degrees). The scale factor is the adjustment factor. To match Tinseth the Scale Factor is set to 112.
I personally do not think that an exponential function is appropriate here. It is believed that the greatest and most variable influence on hop utilisation versus "bigness" is the amount of protein in the wort during the boil, not the actual gravity of the wort. The solubility of alpha-acid does not vary much with gravity, but protein has the effect of absorbing alpha-acid and dragging it out of solution with the trub. Different beers, particularly beers of different recipe (and strength), will have different amounts of protein and therefore different hop utilisation. Twice as much pale malt = twice as much protein = twice as much alpha-acid absorbed - a more or less linear function it would seem, although I doubt if it is quite that simple. In point of fact, the Tinseth implementation is right down on the linear-most part of the exponential curve and the results differ very little from a simple linear implementation.
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Bc = Boil Time Compensation Factor, another number between 0 and 1. This is again an exponential function, and is given by Bc = 1-e^(-t/T). T is the boil time in minutes and "t" is the scale factor, which is in fact the time it takes for isomerisation to reach 63%. Many electrical/electronics engineers will recognise the formula as the same as the time constant for a capacitor. To match Tinseth "t" is set to 25 (actually the reciprocal of Tinseth's 0.04).
Although the exponential curve is the identical shape as a utilisation graph published by one hop merchant, I have a possible theoretical objection to the shape of the curve in that it starts at time-zero with isomerisation occurring immediately at its maximum rate, which may not be true. My argument being that isomerisation is a slow, time-related, process, like most cooking processes, and does not instantaneously occur at maximum rate. There would at least be a significant delay before isomerisation begins, but is more likely to gradually build up from zero, reaching maximum rate after several minutes. An S-shaped (sigmoid) curve is a far more likely scenario (as in one of the other workers' formulae). Of course, in defence of the hop merchant, commercial brewers do not shove bittering hops in the copper for ten minutes, and it would not be an issue if it were not for the habit of home brewers using the same formulae for predicting the bitterness contribution for late hops. The curve represents the duration from time zero, whereas late hops are added towards the end of the boil. Clearly, different utilisations would apply. A sigmoid curve would go a long way to equalising this.
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With Su set to 39.75, the Gc scale factor set to 112, and t set to 25, it matches the Tinseth table spot on. The advantage is just one obvious number needs to be adjusted to tailor each of the parameters. The 39.75 can be adjusted to move the whole utilisation up and down bodily. The scale factor (112) can be adjusted to independently move the "bigness" factor up and down. t can be adjusted to independently move the boil factor up and down. Arguably, pellet hops and whole hops should have different values for t anyway.