Two things popped right out at me in your post. It sounds like you are planning to make starters doing dry yeast. Totally unnecessary and not recommended with dry yeast. Unlike liquid yeast, each package has more than enough yeast cells for a 5 gallon batch. Also by making a starter with dry yeast, you actually end up with less viable yeast. Just rehydrate according to the directions. I think
www.mrmalty.com has more info on that.
The second thing is that you need to be careful about hanging on to extra wort for two long. When making wort you are actually making a growth medium for propagating microorganisms. In other words, something much more ideal for growing stuff than that bowl of leftover spaghetti in the fridge. How long would you consider that spaghetti safe to save? Wort is much more conducive to growing nasties.
I can my starter wort in quart jars. It's all processed for 20 minutes at 15+ psi. The stuff keeps for months this way. The problem with the "sniff test" mentioned above is that you can't smell some of the things that may grow in there, especially botulism. The spores from that aren't killed by boiling in an open kettle since it simply doesn't get hot enough, hence the pressure canning. We get by without pressure cooking our beer because the alcohol prevents the spores from multiplying. Botulism spores themselves are not poisonous in themselves but the toxins produced during reproduction (similar to esters produced by yeast during reproduction) are deadly. Continued exposure to air (botulism is anaerobic) keeps it under control for a little while but increases the chances of other contamination.
In short, if you are not going to use the leftover wort in a day or two, pitch it out. When you do stick it in the fridge, make sure it is cold before sticking a tight lid on it. Putting a tight lid on hot wort will create a partial vacuum in the container which makes the botulism danger higher.
I don't mean to sound alarmist here. It's just a habit from too many years in the food service industry. Most of the time you can probably get away with storing the wort for several days. The risk of spoilage just gets higher and higher each day.
Wayne