Big Chooch wrote:Lennybuzz wrote: The PH is where Im a slacker, I have no idea before or after doughing in. I just know from being in places with both extreems on water that mine is neither extreemly hard nor soft, but somewhere in between.
I understand this isn't that big of a deal and Doc's "relax and have a homebrew" attitude about your stats. However, my OCD is kicking in and I'm very interested in this topic. So I have a question. Don't PH levels indicate the acidity/alkalinity of the water versus the dissolved mineral level (hard/softness)? Are the two proportionate to each other? Hate to kick a dead horse but asking stupid questions is the only way I'll learn.
Mash pH and water pH; related but different. Mash pH is what you're interested in for efficiency, The water pH influences the mash pH.
OK, Think of what you're doing in the mash. You're making the environment happy for the enzymes. All enzymes work best in a particular Temperature and pH range (their optimum). They will work outside this range but slower. The two main enzymes in the mash that we manipulate are the A&B amylases. Generally in AG brewing we use the temp to make this manipulation happen. The "brewers window" is a compromise between the two temp ranges of the A&B amylases (149-152F). This is not the optimal for either. The same is true for the pH ranges for both, it's a compromise. If you get outside the optimal (pH) range/window for these enzymes, production of their substrates is slowed, (like w/ temperature). (i.e.- you won't break down the starches into enough fermentable sugars, and you OG goes down)
Now, let's talk about the effects of water pH on the mash. Normally, (w/o any outside influences) the mash buffers will want things to settle in to a pH range of 5.2-5.4 on it's own (Yeah us!). If you have hard water/high pH and a light grain bill you will have a mash pH that is too high (maybe 5.9). Conversely, if you have dark grains (which are acidic and pull the mash pH down) and soft water (w/ nothing in it to buffer the acidic grains) then you will have a pH that is too low. Even if you hit your temps right on, (you should calibrate your thermometer btw, to make sure) the mash is less efficient if your pH is out.
Mash thickness is also a factor in mash efficiency.



