I agree that water chemistry is not so big a deal for the extract brewer. But as an "advanced extract brewer" I've found that water chemistry does indeed play a roll, outside the mash.
Two main chemicals extract brewers should concern themselves with are calcium and sulphates.
Proper calcium levels are important for clarity, by aiding in protein sedimentation, tannins removal and overall flavor. This reduces chill haze and general cloudiness.
Sulphates play a major roll in hop utilization, yeast flocculation and overall flavor. The famous "extract flavor" is usually a result of high sulphates and clorides.
Since I started tweeking my water, even a very refined pallate would be hard put to identify my beer as as an extract/steeped brew. <rich braces himself for rebuttals>

