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Waterganza Notes: Parts 1 & 2

http://www.thebrewingnetwork.com/forum/viewtopic.php?f=2&t=15639

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Waterganza Notes: Parts 1 & 2

Posted: Thu Jul 09, 2009 2:01 pm
by Logger
I searched the forum hoping that someone had already done this, but didn't find anything, so I sat down and listened to the first 2 parts of the Jamil Show Waterganza and took notes...

Waterganza Notes Part 1:

- Water affects taste in two ways: 1. directly thru impacts of associated minerals, 2. indirectly through pH
- More acidic water provides brighter and dryer characteristics. Too acidic leads to sharp flavors.
- More basic water provides mellower and softer characteristics. Too basic leads to dull and bitter flavors.
- The chloride to sulfate ratio drives teh balance of the beer.
- Chloride = malt enhancer, rounder flavors, 0-250 ppm
- Sulfate = drys out beer, accentuates bitterness
- Calcium and Magnesium (mostly calcium) are typically the hardness minerals
- Bicarbonate (carbonate) drives the alkalinity
- Calcium takes part in a lot of brewing reactions: mash pH, yeast health, flocculation. You need at least 50ppm, but over 150ppm affects pH too much.
- yeast get all the magnezium they need from the malt.
- Bicarbonate levels: 0-50ppm for pale beers
50-150ppm for pale ales up to brown ales
150-250ppm for dark beers (american brown +)
don't go above 300ppm because of buffering capacity of
malts and throw off pH.
- Bicarbonate = total alkalinity as CaCO3
- Sulfate levels: 50-150ppm for normally bitter beers
150-350ppm for hoppy beers
- Sodium and Chloride: 0-150ppm chloride
don't recommend adding sodium (it's just along for the ride)
- Chloride to Sulfate Ratios: C S
1: 0.5 very bitter
1: 0.5 - 0.75 moderately bitter
1: 0.75 - 1.25 relatively balanced
1: 1.25 - 1.5 malty
1: 1.5 - 2 very malty
this is all arm waving!

Part 2:

- due to risidual alkalinity, water pH does not matter
- lactic acid does add a flavor component
- phosphoric acid - neutral flavor, but precipitates calcium phosphate (changes water hardness)
- use salts before acids, but if salts can't get you there use acids
- worry about getting RA correct first, chloride to sulfate ratio second. these two will get you 99% of the way there
- pH = RA
- dark malts are acidic
- add minerals at dough in as the drop in pH allows for dissolution
- check pH 5-15 minutes after dough in
- Calcium chloride will dissolve in sparge water, but most other salts won't
- add salts to mash based on mash water volume, skip sparge additions, add remaining salts to boil kettle


These are otes culled from forum posts by AJDelang:
AJD - The choice between acid and salts depends on the residual alkalinity and the qualities you want in the finished beer. Salts and acids both leave the anion of the acid in the beer but salts also result in a cation being present. For soft beers (pils, etc.) you don't want this. Addition of salts and acids is required at both ends of the hardness spectrum. At the soft end (mash pH 5.7-5.8) ther is no calcium to react with the malt phosphate. At the high end it is the accompanying alkalinity that eats your lunch.
AJD - Any RA less than 50 is workable for most beers. Hardness = good, alkalinity = bad, therefore adding bicarbonate (or carbonate) to brewing water isn't something to do except under unusual circumstances.
AJD - Where sodum is around too much chloride you will get salty tastes

Hope these help somebody! :aaron

Re: Waterganza Notes: Parts 1 & 2

Posted: Sat Jul 11, 2009 12:46 pm
by Thirsty_Monk
This is quick transcript from the show.
Excuse the mess.

Part 3:

Water Analysis:

How To Brew Charter 15 http://www.howtobrew.com/section3/chapter15-3.html

Water report will give us:
Calcium
Magnesium
Tolal Alkalinity as Calcium Carbonate (CACO3) and calculate Residual alcalinity for your water.

For the nomograph of How to brew book (Or spread sheet) and estimate what color range of beer styles will best fit to that water.

May be Bi-carbonate
Total Alkalinity is the most useful number.

Sulfate = Brings up the Bitter profile
Chloride = Malt
Determine flavor profile of final beer.

Residual Alkalinity:
Determines what kind of styles you can brew.
-60 to 0 = good for pale beers
0 to 120 = good for pale amber to amber to copper colors
120 to 250 = good for brown ales, porters and stouts.

You always want to have mash PH 5.2. to 5.4 of mash temp or 5.4 to 5.8 in room temperature.

You want to have at least 50 ppm of Calcium for good fermentation and flocculation.

Calcium Chloride = Gypsum

Water Build:

Czech Pilsner:

Balanced beer in terms of its Chloride to Sulfide ratio. (Maltiness to bitterness) brewed with very light mineral profile.
Start up with distilled water and build up Calcium level to at least 50 ppm.
Chloride to Sulfide ratio keep balance.
Build it up half and half with Gypsum and Calcium Chloride so you get half of the calcium from Gypsum (Calcium Sulfate) and half from Calcium Chloride. That way we have Chloride to Sulfide ratio balanced.

German Pilsner:

Drier form of Pilsner. It has a little more bitter bite.
About the same amount of calcium in water profile but you are going to have more calcium coming from Gypsum (Calcium Sulfate) then from Calcium Chloride.
Medium level of mineral content so Calcium should be somewhere between 65 to 75 ppm.

Munich Helles

Medium level of mineral content so Calcium should be somewhere between 50 to 70 ppm.
You are going to have more calcium coming from Calcium Chloride then from Gypsum (Calcium Solfate).

Dortmunder Export

Balanced beer with higher levels of minerals over all.
Looking for residual alkalinity that support color of the beer at about 4-6 SRM.
Balanced Chloride to sulfide ratio
Go with higher Calcium levels like add some bi-carbonate
Calcium should be somewhere between 200 ppm.
Magnesium 10 - 20 ppm.
150 ppm of total alkalinity.
Chloride to Sulfide ratio balance about 100 ppm from each.

Calculate in grams.
Mash first
then kettle addition especially when building from distiled water.
The only concern during sparging is you do not want to change mash pH such that Mash pH rises to over 6 pH. If you are sparging with distiled water that is not going to happen.
Only then you are sparging with highly alkaline water like Northern Minnesota. that you need to be concerned about pH of mash during sparge and tannin extraction.
If you sparge with distilled water you can sparge with out care in the world.
All you want to do is to have water profile of the beer coming into fermenter.

IPA / ESB
Burton On Trent:
Lot of gypsum.
Build from distilled.
Calcium 100ppm
Add equal amount of caulk (So 4 grams of gypsum and 4 grams of caulk for 5 gal 1054 ) Residuall alc of 6.
200 ppm of sulfate.
To get some maltiness reduce gypsum to half and add Calcium Chloride to the second half.

Dry Stout:

Background bitterns.
Balance Chloride to sulfate may be little bit more on Chloride side.
Residual alkalinity 200
High bi-carbonate water

Best acid to adjust mash Ph
Lactic acid (Add sour flavor in higher concentration if more then 2 mils per 1 gallon)
Phosphoric acid (Take calcium out of solution).

Calcium Sulfate (Gypsum) if in Pale Ale
Calcium Carbonate (Chalk) if in Stouts
Calcium Chloride

5 grams of calcium or less, Add to mash, Stir, Wait 10-15 minutes to take effect. Check it with meter.

Re: Waterganza Notes: Parts 1 & 2

Posted: Sat Jul 11, 2009 2:36 pm
by DBear
Thanks for compiling the water info :jnj Its always helpful to have tips in one place.

Re: Waterganza Notes: Parts 1 & 2

Posted: Mon Jul 13, 2009 7:08 am
by DannyW
- Chloride to Sulfate Ratios: C S
1: 0.5 very bitter
1: 0.5 - 0.75 moderately bitter
1: 0.75 - 1.25 relatively balanced
1: 1.25 - 1.5 malty
1: 1.5 - 2 very malty


Is this part backward? If the 1 = Chloride and the number on the right of the colon is the Sulfate then I think it works the other way

1: 0.5 = more chloride = more malty
1:1 = roughly equal chloride & sulfate = balanced
1: 2 = more sulfate than chloride = bitter

Re: Waterganza Notes: Parts 1 & 2

Posted: Mon Jul 13, 2009 10:17 am
by Junket
DannyW wrote:
- Chloride to Sulfate Ratios: C S
1: 0.5 very bitter
1: 0.5 - 0.75 moderately bitter
1: 0.75 - 1.25 relatively balanced
1: 1.25 - 1.5 malty
1: 1.5 - 2 very malty


Is this part backward? If the 1 = Chloride and the number on the right of the colon is the Sulfate then I think it works the other way

1: 0.5 = more chloride = more malty
1:1 = roughly equal chloride & sulfate = balanced
1: 2 = more sulfate than chloride = bitter


I agree that, as written, the math is not quite right. You can either do what Danny has done and reverse the descriptors, or you can ignore the ratios or at least the "1 :" part and think of the decimal number alone as C divided by S. (ie. 1.5 - 2 is very malty). Thus a higher C (numerator or top) is a number greater than one and is malty, and a higher S (denominator or bottom) is less than one and is bitter. I'm not sure the ramifications of either of these methods on the correlation to the descriptors though. Any ideas which correlates better?

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